It's great for adding highlights and details to watercolor illustrations!
My favorite white ink was tested over blank ink, watercolor, and gouache to find the best.
This ink comes in a bottle and needs to be used with a nib or a small brush. Because of that, it's not as convenient as the pens, but I still like using it. (Affiliate link)
You could use white acrylic paint or white gouache instead. Use a small brush for the best results.
The Uniball Signo pen is probably my favorite. It's just so easy to use. The Posca pen is a close 2nd because I love how opaque it is.